Journal article
Uptake and Incorporation of Al, Cr, V, Zn and Mo in Hematite: Competition, Synergies and Influence on Structural Properties
Journal of hazardous materials, Vol.445, pp.1-11
05/03/2023
Metrics
18 Record Views
UN Sustainable Development Goals (SDGs)
This output has contributed to the advancement of the following goals:
Source: InCites
Abstract
This study investigated multiple (di-, tri- and tetra-)incorporation of selected minor and trace elements (Al3+, Cr3+, V3–5+, Zn2+, Mo6+ and As5+) into hematite. The purpose was to improve understanding of how hematite may control trace element mobility in the environment, and how physical and chemical properties of hematite are impacted by multi-element incorporation at x/Fe molar ratios of up to 10%. Simultaneous structural incorporation of Al±Cr±V±Zn into hematite was achieved, with both synergistic and antagonistic effects occurring between certain element combinations. Cr+Al had synergistic effects on their co-incorporation, while V negatively affected Al incorporation, and both V and Zn negatively affected Cr incorporation. In contrast, Mo was minimally associated with hematite, and As prevented hematite formation completely. X-ray diffraction indicated contraction and expansion of the hematite unit-cell upon substitution was related to the ionic radius of the substituting element in single-element samples, while V predominantly controlled the direction of deviation in multi-element samples. X-ray absorption near-edge structure spectroscopy indicated V was present as a mixture of V3+-V5+, with a higher average V oxidation state associated with multi-element samples. Results provide new insights into trace element geochemistry within hematite, and highlight the importance of multi-element studies to better understand natural and anthropogenic systems.
Details
- Title
- Uptake and Incorporation of Al, Cr, V, Zn and Mo in Hematite: Competition, Synergies and Influence on Structural Properties
- Creators
- G. Scullett-Dean - School of Agriculture and Environment, University of Western Australia, Crawley, WA 6009, AustraliaJ Hamilton - Australian Nuclear Science and Technology OrganisationO Repina - School of Earth and Environmental Sciences, University of Queensland, St Lucia, QLD 4072, AustraliaH.E.A. Brand - Australian Nuclear Science and Technology Organisation, 800 Blackburn Road, Clayton, VIC 3168, AustraliaE.D Burton - Southern Cross UniversityM. Saunders - Centre for Microscopy, Characterisation and Analysis, University of Western Australia, Crawley, WA 6009, AustraliaT.C. Santini - School of Agriculture and Environment, University of Western Australia, Crawley, WA 6009, Australia
- Publication Details
- Journal of hazardous materials, Vol.445, pp.1-11
- Publisher
- Elsevier B.V
- Identifiers
- 991013075222102368
- Copyright
- © 2022 Elsevier B.V. All rights reserved.
- Academic Unit
- Faculty of Science and Engineering; Science
- Language
- English
- Resource Type
- Journal article