Journal article
Porosity in metal-organic framework glasses
Chemical Communications, Vol.52(19), pp.375-3753
25/02/2016
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Source: InCites
Abstract
The porosity of a glass formed by melt-quenching a metal-organic framework, has been characterized by positron annihilation lifetime spectroscopy. The results reveal porosity intermediate between the related open and dense crystalline frameworks ZIF-4 and ZIF-zni. A structural model for the glass was constructed using an amorphous polymerization algorithm, providing additional insight into the gas-inaccessible nature of porosity and the possible applications of hybrid glasses.
Details
- Title
- Porosity in metal-organic framework glasses
- Creators
- A. W Thornton - Commonwealth Scientific and Industrial Research OrganisationK. E Jelfs - Imperial College LondonK Konstas - Commonwealth Scientific and Industrial Research OrganisationC. M Doherty - Commonwealth Scientific and Industrial Research OrganisationA. J Hill - Commonwealth Scientific and Industrial Research OrganisationA. K Cheetham - University of CambridgeT. D Bennett - University of Cambridge
- Publication Details
- Chemical Communications, Vol.52(19), pp.375-3753
- Number of pages
- 4
- Identifiers
- 991013036376602368
- Academic Unit
- Faculty of Science and Engineering; Science
- Resource Type
- Journal article