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Is beudantite a stable host phase of arsenic and lead? New insights from molecular-scale kinetic analyses
Journal article   Open access   Peer reviewed

Is beudantite a stable host phase of arsenic and lead? New insights from molecular-scale kinetic analyses

A.S.M. Fazle Bari, Girish Choppala, Dane Lamb, Jessica L. Hamilton, C I Sathish, Mohammad Rahman, Ravi Naidu, Robert Aughterson and Edward D Burton
Journal of hazardous materials, Vol.480, pp.1-9
05/12/2024
DOI: https://doi.org/10.1016/j.jhazmat.2024.136382
PMID: 39522212
Appears in  Recent Faculty of Science and Engineering Publications
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Abstract

Lead Stability X-ray absorption spectroscopy Arsenic Mineralogy, abandoned mines Toxicity
Beudantite, an As-Pb containing Fe(III) sulfate secondary mineral, is formed via the oxidation of sulfide-rich tailings in mining-impacted regions. The geochemical stability of beudantite plays a key role in controlling the cycling and transport of As and Pb in mine sites. However, the fate of beudantite under dynamic pH conditions and its effect on As and Pb mobility remain elusive. We investigated the mobility dynamics of As and Pb during the dissolution of beudantite under variable pH conditions (2-8) relevant to mine sites by using a complementary suite of analytical methods. Results demonstrate that under acidic pH conditions, aqueous As and Pb content increased slightly, with just 0.7 % and 6.7 % of As and Pb partitioned from the beudantite crystal structure over 56 days. Notably, the rate at which the dissolution of beudantite led to solubilization of elements followed the order Fe > As > Pb within the first 2 h of dissolution. In contrast, the order shifted to Pb > Fe > As after 2 h. Arsenic K-edge X-ray absorption spectroscopy analyses revealed no shifts in As speciation or secondary mineralogical transformation. Here, we show for the first time that beudantite could be considered a relatively stable mineral host for As and Pb over a broad spectrum of environmental conditions. Beudantite can be expected to immobilise metals liberated by the primary weathering of sulfide-rich mine wastes, thereby lowering the risk to the environment and human health resulting from their discharge into the surrounding environment and aquifer.

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