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Published (Version of record)CC BY V4.0, Open Access
Published (Version of record)CC BY V4.0, Open
Journal article
Electro-concentration of urine designed for separation of sodium from nitrogen
Separation and Purification Technology, Vol.276, pp.1-9
01/12/2021
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Abstract
Source-separated urine is a natural liquid fertilizer used by humanity for millennia. Urine use in modern nutrient recycling can be hindered by high relative salinity, non-optimal macro-nutrient ratio, presence of pathogens, and organic micropollutants. In this study, an electrochemical system was used to oxidize and concentrate synthetic urine into a product concentrate and a waste concentrate, also releasing a treated low nutrient load effluent. The system comprised two electrochemical reactors with separate concentration chambers and two circulation loops. Each circulation loop was comprised of two electrodes of opposite polarity, one from each of the two reactors. The pH levels in each loop were controlled electrochemically without chemical addition, allowing for selective ammonium (total ammonium nitrogen, TAN) and sodium (Na) separation into the product concentrate and the waste concentrate, respectively. In addition to pH, which was controlled by the relative current of the two reactors, the concentrate characteristics were controlled by the absolute potentials applied, affecting the oxidation reactions present. The double reactor system was able to divert a waste concentrate with a relative volume of 4% vs. the feed. The waste concentrate contained 14% of the influent Na but only 1% of the influent TAN, effectively removing sodium while removing very little TAN. This demonstrates a proof of concept for Na/TAN ion separation using electrochemical pH control. Compared to a single reactor control, between 12 and 17% reduction in Na/TAN ratio was achieved in the product concentrate with a specific energy consumption of 11–22 kWh kgN−1. A total TAN recovery of 56–76% into the product concentrate was demonstrated. A wide range of tailoring parameters could be used for optimizing the redox chemistry and product characteristics. This novel technology shows promise for optimization for fertilizer production from source-separated urine.
Details
- Title
- Electro-concentration of urine designed for separation of sodium from nitrogen
- Creators
- Johannes Jermakka - Faculty of Engineering and Natural Sciences, Tampere University, Finland. Permanent address: Tampere University, Faculty of Engineering and Natural Sciences, PO Box 541, 33101 Tampere, FinlandEmma Thompson Brewster - Southern Cross UniversityStefano Freguia - Department of Chemical Engineering, The University of Melbourne, Parkville, AustraliaPablo Ledezma - Advanced Water Management Centre, The University of Queensland, Brisbane, AustraliaMarika Kokko - Faculty of Engineering and Natural Sciences, Tampere University, Finland. Permanent address: Tampere University, Faculty of Engineering and Natural Sciences, PO Box 541, 33101 Tampere, Finland
- Publication Details
- Separation and Purification Technology, Vol.276, pp.1-9
- Publisher
- Elsevier Ltd
- Identifiers
- 991012948481902368
- Copyright
- © 2021 The Authors. Published by Elsevier B.V. This is an open access article under the CC BY license (http://creativecommons.org/licenses/by/4.0/).
- Academic Unit
- Faculty of Science and Engineering; School of Environment, Science and Engineering; Engineering
- Language
- English
- Resource Type
- Journal article