A comparative study of CO2 utilization in methanol synthesis with various syngas production technologies

This paper explores a possible ‘methanol economy’ transition strategy—a novel carbon capture and utilization (CCU) configuration for methanol (MeOH) production (CCU–MeOH). In this CCU–MeOH, the captured CO₂ is co-fed with natural gas (NG) to produce syngas suitable for MeOH synthesis. The main objective of this work is to compare two aspects, namely CO₂ emission intensity and the extent of methane reliance, of six CCU–MeOH scenarios derived from four reforming methodologies (steam methane reforming (SMR), dry methane reforming (DMR), bireforming and trireforming). Among the studied CCU–MeOH scenarios, Scenario 2 (DMR with H₂ addition) significantly outperformed the other scenarios by 12.7% and 22% on average in terms of CO₂ emission intensity and methane reliance, respectively. The outperformance of Scenario 2 in CO₂ emission intensity is found to originate from a 22% reduction in CH₄ consumption on average compared to the other scenarios. In intermediate term, Scenario 2 may provide an attractive option for transitioning into ‘methanol economy’ of the future.